Connect your PlayStation VR to your PS5 console to enjoy supported PS VR games. To set up your PS VR with your PS5 console you?ll need your PlayStation Camera* for PS4 and a PlayStation Camera adaptor (no purchase necessary).

*Playing PS VR games on a PS5? console requires a PS VR headset, PlayStation®Camera for PS4? (Model CUH-ZEY1 or CUH-ZEY2) and a PlayStation®Camera adaptor (no purchase required. Visit playstation.com/camera-adaptor for details). For the best PS VR experience on PS5 we recommend using a DUALSHOCK®4 wireless controller. Selected games may require PlayStation®Move motion controllers or be compatible with the PlayStation®VR aim controller. The new HD camera for PS5 is not compatible with PS VR. The PS VR headset, PS Camera, DUALSHOCK 4 wireless controller, PS Move controllers and PS VR aim controller are all sold separately from PS5.
https://www.playstation.com/en-us/ps5/

...